isomerization

Same atoms, different arrangement

Isomerization is a chemical process in which a molecule is transformed into a different arrangement of the same atoms—a structural rearrangement without gaining or losing anything.

The result is an isomer: same molecular formula, different configuration.

The process is important in petroleum refining, where straight-chain hydrocarbons are converted to branched forms that burn more efficiently in engines.

mechanism

rearrangement

Altered ordering of elements

ring-opening · keto-enol · skeletal

isomers

stereoisomers

Spatially distinct molecular forms

constitutional · optical · chirality · axial · equatorial · meso

catalysis

catalyst

Agent enabling change

  • enzymeProtein that hastens reactions
  • zeolitePorous aluminosilicate mineral
  • platinumDense precious silvery metal

nickel · palladium · active site · substrate · selectivity · heterogeneous · homogeneous · reforming · industrial

thermodynamics

equilibrium

State of balance

endothermic · barrier · free energy · reversible · spontaneous · kinetics · heat · stability · favorable · unfavorable

applications

petroleum refining

Crude oil distillation industry

vision · drug metabolism · biodiesel · polymerization · fatty acids · vitamin A · carotenoids · industrial chemistry

Categories
Opposites
chemical reaction type

isomerizationdecomposition

Breakdown into simpler parts

synthesis · polymerization · fragmentation · degradation · condensation

molecular stability/change

isomerizationstructural stability

Ability to bear loads

structural change outcome

isomerizationbond cleavage

Breaking molecular connections

cross-linking · chemical stability

Family

cis-trans isomers, isomer, isomers, isomerized

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