alkylation

Adding carbon chains

Alkylation is a chemical process that attaches an alkyl group—a fragment derived from a hydrocarbon—to another molecule.

In petroleum refining, alkylation combines light hydrocarbons to produce high-octane gasoline components.

In organic chemistry and pharmaceuticals, the process modifies molecules to alter their properties: DNA alkylation can cause mutations.

synthesis

substitution

Exchange of one for another

nucleophile · electrophile · halide · mechanism · reactivity · esterification · amination · sulfonation · hydrocarbon · organic

biochemistry

DNA

Hereditary code molecule

guanine · mutagenesis · chemotherapy · nitrogen mustard · base pair · repair · methylation · lesion · cytotoxic · nucleotide

refining

octane

Petroleum hydrocarbon measure

paraffin · isomerization · HF · sulfuric acid · refinery · fuel · blending · branching · butene · propylene

mechanism

SN1

One-step nucleophilic replacement

inversion · retention · rearrangement · activation energy

Opposites
chemical modification direction

alkylationcleavage

Tendency to split cleanly

hydrolysis · elimination · cracking · decarboxylation

functional group transformation type

alkylationoxidation

Losing electrons chemically

hydrolysis · reduction · decarboxylation · desaturation · sulfonation

molecular complexity change

alkylationdegradation

Decline in condition

decomposition · fragmentation · catabolism · pyrolysis · bond cleavage

Family

alkylating

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